4-Chloro-3-methylcrotonic Acid Derivatives and Phosphonates

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N-(4-Chloro-3-nitro­phen­yl)succinamic acid

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N-(3-Chloro-4-methyl­phen­yl)maleamic acid

In the title compound, C(11)H(10)ClNO(3), the dihedral angle between the benzene ring and the amide group is 6.6 (10)° and an intramolecular O-H⋯O hydrogen bond occurs. In the crystal, molecules are linked by N-H⋯O hydrogen bonds, generating C(7) zigzag chains.

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N-(4-Chloro-3-methyl­phen­yl)succinamic acid

The title compound, C(11)H(12)ClNO(3), crystallizes with two independent mol-ecules in the asymmetric unit in which the dihedral angles between the benzene ring and the amide group are 55.0 (2) and 28.2 (3)°. The two independent mol-ecules are linked by an N-H⋯O hydrogen bond. In the crystal, mol-ecules form inversion dimers via pairs of O-H⋯O hydrogen bonds. These dimers are linked into sheets...

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N-(4-Chloro-3-nitro­phen­yl)maleamic acid

In the mol-ecule of the title compound, C(10)H(7)ClN(2)O(5), the acyclic C=C double bond is cis configured. The C=O and O-H bonds of the acid group are in a relatively rare anti position to each other, due to the donation of intramolecular hydrogen bond to the amide by the carboxyl group. The nitro group is significantly twisted [dihedral angle = 66.9 (3)°] out of the plane of the remaining ato...

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N-(3-Chloro-4-methyl­phen­yl)succinamic acid

In the crystal structure of the title compound, C(11)H(12)ClNO(3), the asymmetric unit contains two independent mol-ecules. The N-H bond in the amide segment is anti to the meta-Cl atom in the benzene ring, in both molecules. The amide and carboxyl C=O bonds are also anti to each other and anti to the H atoms on the adjacent -CH(2) groups. Furthermore, the C=O and O-H bonds of the acid group ar...

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ژورنال

عنوان ژورنال: Bulletin of the Chemical Society of Japan

سال: 1962

ISSN: 0009-2673,1348-0634

DOI: 10.1246/bcsj.35.1743